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Impact of Nonzero Intercept Gas Transfer Velocity Parameterizations on Global and Regional Ocean-Atmosphere CO2 Fluxes ArchiMer
Ribas-ribas, Mariana; Battaglia, Gianna; Humphreys, Matthew P.; Wurl, Oliver.
Carbon dioxide (CO2) fluxes between the ocean and atmosphere (FCO2) are commonly computed from differences between their partial pressures of CO2 (pCO(2)) and the gas transfer velocity (k). Commonly used wind-based parameterizations for k imply a zero intercept, although in situ field data below 4 m s(-1) are scarce. Considering a global average wind speed over the ocean of 6.6 m s(-1), a nonzero intercept might have a significant impact on global FCO2. Here, we present a database of 245 in situ measurements of k obtained with the floating chamber technique (Sniffle), 190 of which have wind speeds lower than 4 m s(-1). A quadratic parameterization with wind speed and a nonzero intercept resulted in the best fit for k. We further tested FCO2 calculated with...
Tipo: Text Palavras-chave: Gas transfer velocity; Low wind speed; Carbon dioxide; Ocean-atmosphere CO2 flux; Carbon cycle.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00675/78732/80994.pdf
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Mesoscale Temporal Wind Variability Biases Global Air–Sea Gas Transfer Velocity of CO2 and Other Slightly Soluble Gases ArchiMer
Gu, Yuanyuan; Katul, Gabriel G.; Cassar, Nicolas.
The significance of the water-side gas transfer velocity for air–sea CO2 gas exchange (k) and its non-linear dependence on wind speed (U) is well accepted. What remains a subject of inquiry are biases associated with the form of the non-linear relation linking k to U (hereafter labeled as f(U), where f(.) stands for an arbitrary function of U), the distributional properties of U (treated as a random variable) along with other external factors influencing k, and the time-averaging period used to determine k from U. To address the latter issue, a Taylor series expansion is applied to separate f(U) into a term derived from time-averaging wind speed (labeled as ⟨U⟩, where ⟨.⟩ indicates averaging over a monthly time scale) as currently employed in climate...
Tipo: Text Palavras-chave: Carbon dioxide; Gas transfer velocity; Time-averaging; Wind speeds.
Ano: 2021 URL: https://archimer.ifremer.fr/doc/00687/79949/82869.pdf
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On which timescales do gas transfer velocities control North Atlantic CO2 flux variability? ArchiMer
Couldrey, Matthew P.; Oliver, Kevin I. C.; Yool, Andrew; Halloran, Paul R.; Achterberg, Eric P..
The North Atlantic is an important basin for the global ocean's uptake of anthropogenic and natural carbon dioxide (CO2), but the mechanisms controlling this carbon flux are not fully understood. The air-sea flux of CO2, F, is the product of a gas transfer velocity, k, the air-sea CO2 concentration gradient, Delta pCO(2), and the temperature-and salinity-dependent solubility coefficient, alpha, k is difficult to constrain, representing the dominant uncertainty in F on short (instantaneous to interannual) timescales. Previous work shows that in the North Atlantic, Delta pCO(2) and k both contribute significantly to interannual F variability but that k is unimportant for multidecadal variability. On some timescale between interannual and multidecadal, gas...
Tipo: Text Palavras-chave: Carbon flux; Gas transfer velocity; Carbon cycle; Ocean model; Climate dynamics; Variability.
Ano: 2016 URL: https://archimer.ifremer.fr/doc/00383/49418/49868.pdf
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